Breakfast at hotel. Morning drive one hour to visit Padua. See the world-famous frescoes by Giotto in the Scrovegni Chapel . Walk through one of Europe's largest public squares, Prato della Valle. See the Basilica of St Anthony. Go through the narrow streets of the city center where you will see the beautiful squares full of shops and café and you could enjoy a typical coffee at the historical Caffé Pedrocchi (at your own expense). 

Then drive to check in the hotel in Venice. Free and overnight.